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Emulsification and polymerization of alkyd resins

紀錄類型:	書目-電子資源 : 單行本
正題名/作者:	Emulsification and polymerization of alkyd resins/ Jan W. Gooch.
作者:	Gooch, Jan W.
出版者:	New York :Kluwer Academic/Plenum Publishers,c2002.
面頁冊數:	1 online resource (xxii, 223 p.) :ill.
標題:	Alkyd resins. -
電子資源:	Click here for online access to this book (查閱全文) (EBSCO eBook)
ISBN:	0306475545 (electronic bk.)
ISBN:	9780306475542 (electronic bk.)

Emulsification and polymerization of alkyd resins
Gooch, Jan W.1946-

Emulsification and polymerization of alkyd resins[electronic resource] /Jan W. Gooch. - New York :Kluwer Academic/Plenum Publishers,c2002. - 1 online resource (xxii, 223 p.) :ill. - Topics in applied chemistry. - Topics in applied chemistry..

Includes bibliographical references (p. 215-218) and index.

Machine generated contents note: I -- I -- 1. ALKYD RESINS, VEGETABLE OILS AND AUTOXIDATIVE -- POLYMERIZATION -- 1.1. Goals of Research and Development in Alkyd Emulsions -- 1.2. Historical Background of Alkyds, Oils and Emulsions -- 1.2.1. Vegetable Oils and Resins -- 1.2.2. Autoxidative Polymerization of Vegetable Oils and -- Resins -- 1.2.3. Emulsified Oils and Resins -- 1.3. Theoretical Considerations -- 1.3.1. Intrinsic Viscosity -- 1.3.2. Hydrophile-Lipophile Balance (HLB) -- 1.3.3. Diffusion of Oxygen in an Emulsion -- 1.3.4. Solubility of Air and Oxygen in Aqueous Phase -- 1.3.5. Swelling Ratio -- 1.4. Justification for Research and Development -- 2. SYNTHESIS AND POLYMERIZATION OF ALKYDS -- 2.1. Alkyd Synthesis Procedure -- 2.2. Emulsification Procedure -- 2.3. Autoxidation Procedure -- 2.4. Materials -- 2.5. Characterization -- 2.5.1. Emulsion Particle Size -- 2.5.2. Emulsion Characterization -- 2.5.3. Film Characterization -- 2.5.4. Intrinsic Viscosity Measurement -- 2.5.5. Swell Ratio -- 2.5.6. Turbidimetric Measurement of Swelling Ratio -- 2.5.7. Dissolved Oxygen in Aqueous Phase -- 3. EMULSION AND KINETIC STUDIES OF AUTOXIDATIVE -- POLYMERIZATION -- 3.1. Emulsifier Studies -- 3.1.1. Emulsifier Sources and Chemical Structures -- 3.1.2. Emulsifiers and Emulsion Stability -- 3.1.3. Emulsifiers and Freeze-Thaw Stability -- 3.1.4. Emulsifiers and Film Characterization -- xiii -- 3.2. Phase Ratio and Co-Solvent Study -- 3.2.1. Solvent Alkyd Emulsions -- 3.2.2. Co-Solvent Containing Emulsions -- 3.3. Studies on the Autoxidative Crosslinking of Emulsified -- Soya Oil -- 3.3.1. Autoxidation Reaction of Emulsified Soya Oil -- 3.3.2. Catalysis of Autoxidation Reaction of Soya Oil -- 3.4. Studies of the Autoxidative Crosslinking of Emulsified -- Alkyd Particles -- 3.4.1. Autoxidation Reaction of Emulsified Alkyd Resins -- 3.4.2. Non-catalyzed Autoxidation Reaction -- 3.4.3. Benzoyl Peroxide Catalysis in the Alkyd Phase -- 3.4.4. Cobalt Naphthenate Catalysis in Aqueous Phase -- 3.4.5. Autoxidized Emulsion Characterization -- 3.4.6. Post pH-Adjustment of Autoxidized Emulsion -- 3.4.7. pH Adjustment Prior to the Autoxidation -- 3.4.8. Cobalt Naphthenate Catalysis in Alkyd Phase -- 3.4.9. Post-Addition of Emulsifier -- 3.4.10. pH Effect on Reaction Rate -- 3.4.11. Increased Oxygen Concentration and Catalysis -- 3.4.12. Scanning Electron Microscopy -- 3.4.13. Water Clean-Up of Emulsion -- 3.4.14. Comparison to Alkyd-Solvent System -- 3.4.15. Effect of Emulsifier Structure on Reaction Rate -- 3.5. Kinetic Study -- 3.5.1. Oxygen Concentration Relationship -- 3.5.2. Correlation of Swell Ratio and Percent Transmittance -- 3.5.3. Catalysis Effect -- 3.5.4. Temperature Effect -- 3.5.5. Agitation Rate Effect -- 3.5.6. Molecular Weight Effect -- 3.6. Studies on Emulsion Particle Size -- 3.6.1. Particle Size with Reaction Time -- 3.6.2. Average Particle Size with Homogenization -- 3.6.3. Particle Size after One Year of Shelf Life -- 3.7. Alkyd Oil Length and Conjugation Study -- 3.7.1. Alkyd Oil Length Study -- 3.7.2. Alkyd Conjugation Study -- 4. EXPERIMENTAL RESULTS, RESEARCH -- AND COMMERCIALIZATION OF TECHNOLOGY -- 4.1. Autoxidative Crosslinking of Vegetable Oil -- 4.2. Autoxidative Crosslinking of Vegetable Oil Alkyds -- 4.3. Emulsification -- 4.4. Continuing Research and Developments -- 4.5. Commercialization of Alkyd Emulsions -- APPENDIX -- FIGURES -- APPENDIX -- TABLES -- REFERENCES -- INDEX

This original research, published here for the first time in book format, describes in detail an entirely new process for preparing emulsions and alkyd resin emulsions, leading to many applications, foremost among them the formulation of new paints. This research has also spawned the international field of alkyd and alkyd-hybrid miniemulsions. Pioneering technology is presented for the emulsification of alkyd resins and vegetable oils used in coatings, adhesives, and inks applications. Essential technical information is provided for researchers and manufacturers involved in the emulsification of resins, oils, and pigments. Emulsification and Polymerization in Alkyd Resins is an indispensable reference book for every type of coatings and resins manufacturer or research group.

ISBN: 0306475545 (electronic bk.)Subjects--Topical Terms:

1000071937
Alkyd resins.
Index Terms--Genre/Form:

172687
Electronic books.

LC Class. No.: TP945 / .G66 2002eb

Dewey Class. No.: 668/.372

Emulsification and polymerization of alkyd resins
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300 $a 1 online resource (xxii, 223 p.) : $b ill.
490 1 $a Topics in applied chemistry
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505 0 $a Machine generated contents note: I -- I -- 1. ALKYD RESINS, VEGETABLE OILS AND AUTOXIDATIVE -- POLYMERIZATION -- 1.1. Goals of Research and Development in Alkyd Emulsions -- 1.2. Historical Background of Alkyds, Oils and Emulsions -- 1.2.1. Vegetable Oils and Resins -- 1.2.2. Autoxidative Polymerization of Vegetable Oils and -- Resins -- 1.2.3. Emulsified Oils and Resins -- 1.3. Theoretical Considerations -- 1.3.1. Intrinsic Viscosity -- 1.3.2. Hydrophile-Lipophile Balance (HLB) -- 1.3.3. Diffusion of Oxygen in an Emulsion -- 1.3.4. Solubility of Air and Oxygen in Aqueous Phase -- 1.3.5. Swelling Ratio -- 1.4. Justification for Research and Development -- 2. SYNTHESIS AND POLYMERIZATION OF ALKYDS -- 2.1. Alkyd Synthesis Procedure -- 2.2. Emulsification Procedure -- 2.3. Autoxidation Procedure -- 2.4. Materials -- 2.5. Characterization -- 2.5.1. Emulsion Particle Size -- 2.5.2. Emulsion Characterization -- 2.5.3. Film Characterization -- 2.5.4. Intrinsic Viscosity Measurement -- 2.5.5. Swell Ratio -- 2.5.6. Turbidimetric Measurement of Swelling Ratio -- 2.5.7. Dissolved Oxygen in Aqueous Phase -- 3. EMULSION AND KINETIC STUDIES OF AUTOXIDATIVE -- POLYMERIZATION -- 3.1. Emulsifier Studies -- 3.1.1. Emulsifier Sources and Chemical Structures -- 3.1.2. Emulsifiers and Emulsion Stability -- 3.1.3. Emulsifiers and Freeze-Thaw Stability -- 3.1.4. Emulsifiers and Film Characterization -- xiii -- 3.2. Phase Ratio and Co-Solvent Study -- 3.2.1. Solvent Alkyd Emulsions -- 3.2.2. Co-Solvent Containing Emulsions -- 3.3. Studies on the Autoxidative Crosslinking of Emulsified -- Soya Oil -- 3.3.1. Autoxidation Reaction of Emulsified Soya Oil -- 3.3.2. Catalysis of Autoxidation Reaction of Soya Oil -- 3.4. Studies of the Autoxidative Crosslinking of Emulsified -- Alkyd Particles -- 3.4.1. Autoxidation Reaction of Emulsified Alkyd Resins -- 3.4.2. Non-catalyzed Autoxidation Reaction -- 3.4.3. Benzoyl Peroxide Catalysis in the Alkyd Phase -- 3.4.4. Cobalt Naphthenate Catalysis in Aqueous Phase -- 3.4.5. Autoxidized Emulsion Characterization -- 3.4.6. Post pH-Adjustment of Autoxidized Emulsion -- 3.4.7. pH Adjustment Prior to the Autoxidation -- 3.4.8. Cobalt Naphthenate Catalysis in Alkyd Phase -- 3.4.9. Post-Addition of Emulsifier -- 3.4.10. pH Effect on Reaction Rate -- 3.4.11. Increased Oxygen Concentration and Catalysis -- 3.4.12. Scanning Electron Microscopy -- 3.4.13. Water Clean-Up of Emulsion -- 3.4.14. Comparison to Alkyd-Solvent System -- 3.4.15. Effect of Emulsifier Structure on Reaction Rate -- 3.5. Kinetic Study -- 3.5.1. Oxygen Concentration Relationship -- 3.5.2. Correlation of Swell Ratio and Percent Transmittance -- 3.5.3. Catalysis Effect -- 3.5.4. Temperature Effect -- 3.5.5. Agitation Rate Effect -- 3.5.6. Molecular Weight Effect -- 3.6. Studies on Emulsion Particle Size -- 3.6.1. Particle Size with Reaction Time -- 3.6.2. Average Particle Size with Homogenization -- 3.6.3. Particle Size after One Year of Shelf Life -- 3.7. Alkyd Oil Length and Conjugation Study -- 3.7.1. Alkyd Oil Length Study -- 3.7.2. Alkyd Conjugation Study -- 4. EXPERIMENTAL RESULTS, RESEARCH -- AND COMMERCIALIZATION OF TECHNOLOGY -- 4.1. Autoxidative Crosslinking of Vegetable Oil -- 4.2. Autoxidative Crosslinking of Vegetable Oil Alkyds -- 4.3. Emulsification -- 4.4. Continuing Research and Developments -- 4.5. Commercialization of Alkyd Emulsions -- APPENDIX -- FIGURES -- APPENDIX -- TABLES -- REFERENCES -- INDEX
520 $a This original research, published here for the first time in book format, describes in detail an entirely new process for preparing emulsions and alkyd resin emulsions, leading to many applications, foremost among them the formulation of new paints. This research has also spawned the international field of alkyd and alkyd-hybrid miniemulsions. Pioneering technology is presented for the emulsification of alkyd resins and vegetable oils used in coatings, adhesives, and inks applications. Essential technical information is provided for researchers and manufacturers involved in the emulsification of resins, oils, and pigments. Emulsification and Polymerization in Alkyd Resins is an indispensable reference book for every type of coatings and resins manufacturer or research group.
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